Concentrated Solar for Infrastructure and Fuel
Looking for low-carbon industrial-scale replacements to our CO2 emitting ways.
Goals
Reduce cement/sand/concrete consumption
- concrete is 2nd most consumed material, after water
- 3t / human / year. Developping countries consume most.
- cement production = 8% global CO2 emissions
- 1kg cement = 1kg CO2
- concrete sand reserves are depleted
- and desert sand is not a suitable replacement being too uniform
Towards carbon-free ammonia production
- NH3 is 2nd most synthetized chemical
- most polluting molecule: 1 kg NH3 ~ 3 kg CO2
- used half as fertilizer, half for nylon, explosives, detergents, …
- NH3 is energy dense: potential for carbonless gasoil fuel replacement
- NH3 stores easily, unlike H2
- pollution driven by Haber-Bosch process (making H2 from CH4/oil)
- (2021) Sustainable Ammonia Production Processes
- (2021) Cutting the cost of splitting water
Means
Markus Kayser’s Solar Sinter
- (2011) Markus Kayser’s Solar Sinter
- Thesis (2017) Towards swarm-based design : distributed and materially-tunable digital fabrication across scales
- Page 41. Lens: 1.4 x 1.0 m, USD600
- (2012) Design of a Solar Sand Printer
Large Fresnel lenses
- 1.1 x 1.1m @ CHF750
- 1.450 x 1.115m @ EUR100
- via email: delivered in a roll; should top at 700-800C though
- flatscreen TVs larger than 60 inches contain a Fresnel lens of at least close to 1m2
ESA’s Lunar Soil 3D Printer
- Building a lunar base with 3D printing
- European Union’s Horizon 2020 RegoLight Project
Optical Fibers to conduct solar radiation
- (2016) Optical design of a Fresnel concentrating solar system for direct transmission of radiation through an optical fibre bundle
- the average transmission per metre length of fibre is found to be 52%
- Two thirds of the loss is due to the absorption in the gaps between the individual fibres.
- Luís Guerra Rosa
- 2020: Cable-Heat: Low-angle incident beam for the use of optical fibre bundles to conduct concentrated solar radiation.
- kilowatt power over fiber POF
- (2007) Optical Fiber Tips and Their Applications
- optical fiber daylighting system
- 290 DS Tubular Skylight
- Diamond Dome SUNPIPE
- Parens’ SP4 PRODUCT SPECIFICATION
- via email: quoted at 15k-50k EUR
- Optoelectronic light pipes?
Alternatives to concrete
- Omlab’s MAACQ: CaCO3 + cellulose + Kaumera + H20
- replace cement with smarter concrete blocks. lego type shapes
- MARSHA AI SPACEFACTORY’S MARS HABITAT
- testing concrete properties
- (2018) Thermal treatment of desert sand to produce construction material
- cost to transport sand
- 15-20$ cost per cubic yard
- 50-150$ delivery cost
Very high temperature nozzle
- 3d printing deposit powder while fusing
- (2015) MIT’s Glass 3D printer
- alumina zircon silicone nozzle
- video: Neri Oxman / Mediated Matter, MIT Media Lab - Glass
- High purity graphite crucible 20EUR
- probably up to ~1000C
House-scale 3D Printer: the 3DWASP
Cable-driven parallel robots
- wikipedia on CDPRs
- stadium sizes already achieved
- Packages related to simulation and control of cable-driven parallel robots.
- (2020) SISTEMA AUTOCALIBRABLE PARA PLATAFORMA ROBÓTICA MANIOBRADA MEDIANTE CABLES
- A Matlab library for cable driven parallel robots.
- (2018) Development of a parametric cable driven planar robot
- Hangprinter: cable-driven RepRap
Laser Sintering
- Open-source Selective Laser Sintering
- solar pumped laser
- (2021) Laser Sintering on Sand Made 3D Printer
- (2003) Direct laser sintering of a silica sand
Sand Babel: Solar-Powered Twisting Skyscrapers 3D-Printed With Desert Sands
A very large structure to slow down dune progression / stop desertification
- 3D print intricate tree root systems
- Magnus Larsson: Turning dunes into architecture
Vitrified desert sand
- (2014) Properties of Desert Sand and CMAS Glass (NASA)
- Bulk density of CMAS glass was 2.69 g/cc
- Young’s modulus 92 GPa
- Shear modulus 36 GPa
- Poisson’s ratio 0.28
- showed weight loss of approx. 35 percent due to decomposition of CaCO3 and CaSO4.2H2O when heated to 1400 C
- stronger than concrete in compression, even iron
- but does reject a third in weight as NOx & SOx
- Emissions to produce 1t of industrial glass
- Consommation de matières premières naturelles: 920 kg
- Consommation de matières premières de synthèse: 256 kg
- Consommation de matières totales : 1176 kg
- Consommation de calcin: 0 kg
- Consommation énergétique: 1200 kWh
- Consommation en équivalent fuel: 105 kg
- Emissions de CO2 issues des matières premières: 174 kg
- Emissions de CO2 issues du fuel: 336 kg
- Emissions de CO2 total: 510 kg
- Emissions de poussières: 0,3 kg
- Emissions de SOx: 4,0 kg
- Emissions de NOx: 2,0 kg
(510*100)/(1176+105) = 39.8%
of materials + fuel is emited as CO2(174*100)/1176 = 14.8%
of materials emited as CO2
- (1954) Thermal decomposition of calcium sulfate
- CaO, CO2, SO2, S2, H2S, CaS, H2O
- => potentially vitrifying desert sand emits 15-35% of its mass as CO2
- 65-85% less than concrete
- however NOx SOx outgassing needs handling
Already in industry
- thin printable powder Nylon (PA12) Powder, Sintratec
- Melt Point 176 C, 348.8F
- Stable Temp (Max) 130C, 266F
- Bending Stress (Max) 43.1 MPa
- Tensile Stress (Max) 47.8 MPa
- Tensile Modulus (Max) 1750 MPa
- Particle Size 0.06mm (60 micron)
- Volume (1kg) 2L, 2000cm^3, 122in^3
- Fast, high volume 3D printing tech
- (2018) Sandhelden: tapping into the bathroom design market with 3D sand printing
- manual cement block making machine >800EUR
- automated concrete blocks making machine >10kUSD
- (2017) The Cronus: Mutli-Head 3D Printing
Solar thermal H2 / NH3 production processes
- (2011) Solar Thermochemical Hydrogen Production Research (STCH): Thermochemical Cycle Selection and Investment Priority
- energy.gov Hydrogen Production: Thermochemical Water Splitting
- long-term technology pathway, with potentially low or no greenhouse gas emissions
- Typically direct cycles are less complex with fewer steps, but they require higher operating temperatures compared with the more complicated hybrid cycles.
- Low CO2 Ammonia with electrochemistry, water splitting
- (2020) Electrification of Ammonia Synthesis
- optimizing processes
- (2020) Building a sustainable industrial and energy infrastructure
- thyssenkrupp doing large scale electrolysis
- (2020) GREEN AMMONIA AT OIL & GAS SCALE
- (2020) Electrification of Ammonia Synthesis